#1 Jennifer Aniston and Brad Pitt
This duo was everybody’s favourite. They were both huge superstars who managed to find each other in that glamorous world. On top of all, it all seemed to be working out, at least until Angelina Jolie showed up. During the set of Mr. and Mrs. Smith they got to know each other and Brad fell for her, announcing his divorce with Aniston shortly after that and ending the seven-year-long fairytale with Jennifer.